A little Soldering Theory: As metals approach their melting point the crystal molecules move apart, providing microscopic space for other molecules to enter.
Hard soldering is the attempt to introduce an alloy that melts at that point and by moving into those spaces joins two pieces together.
Soft Soldering uses alloys that melt around 1/3 the melting point of the metal to be soldered.
It/s strength comes from it's ability to cling to CLEAN metal surfaces.
Available in your choice of sheet or wire, Silver Solder comes in at least three melting points:
German Silver, Nickel Silver, White Brass (Usually Cu 60%, Ni 20%, Zn 20%) has a melting point of up to 1450
oC or 2642
oF which can not normally be achieved with a propane torch.
(or 75% copper and 25% nickel used in the United States nickel.)
Silver 999.9 fine Melting point: 960.5
o, 1761
oF
Sterling 92.5, Cu 7.5 Melting point: 893
oC, 1640
oF
Coin Silver 90, Cu 10 Melting point: 879
oC, 1615
oF
From some suppliers,
Hard Grade Silver Solder melts at 741° C, 1365° F - good to start projects.
Medium Grade Silver Solder melts at 691° C, 1275° F - good in middle of projects.
Easy flow - Easy Grade Silver Solder melts at 671° C, 1240° F - best to finish with so you don't mess up what has gone before.
I always bought sheet, cut it into 1/8" strips (still attached at the end) then into 1/8" squares (pallions) and kept them in an old cold cream jar.
I never thought about purchasing the wire form and rolling or hammering it flat, then cutting it into pallions. That may have been easier.
Fluxes:
Borax: melts at 75
oC, 167
oF Possibly the most commonly used flux world wide, available in the laundry isle of your grocery store.
Mix with water into a paste and use as needed. It provides oxide protection and leaves a glassy skin that is easily washed off.
Sparex #1 for ferrous metals
Sparex #2 for all non ferrous metals
Handy Flux, Battern's Flux, Boric Acid & Alcohol, Prips Flux, Cupronil, Hydrogen peroxidemix two parts hp with the same amount of Sparex 2 and one part water. Pickle first in Sparex, then in this mixture to remove any pink skin from brass.
Heat the metal and let the metal melt the solder. It is best to move the flame in circles so you don't melt a part. Solder will follow heat so you can heat from underneath and draw the solder into and along a joint.
With small projects a soldering iron may be sufficient. For larger projects you may prefer propane canisters, natural gas/air, oxy/propane, oxy/acetylene, or air/acetylene.

As the solder heats up it will pull into a ball. If the melted ball is hotter than the metal, it may jump away.
If the metal is hotter than the solder, the solder will ball up, then flatten out, more and more until it no longer holds the two parts together, but instead has just become a coating.
Troubleshooting1. Incomplete or unsoldered joints: Metal was dirty, no flux, not enough heat, too much heat.
2. Solder balls up: Flame applied directly to the solder instead of the metal, metal or solder may be dirty, heat is flowing away from the joint.
3. Solder jumps to one side: One side is hotter than the other. Reflux and try again.